Construct · 1 fields · 1 citations

A-value: a standalone construct

One name. One construct. A landmark on the map.

● anchor · a standalone construct Nearest construct by meaning·not indexed
A-value1 CONSTRUCTA-valueWINSTEIN · ORGANIC CHEMISTRY

A single standalone construct; nearby constructs are located against it in the Collider. Tap a field for its definition, unit, and measures.

Organic chemistry

the free energy difference between the axial and equatorial positions of a substituent on cyclohexane, used as a measure of its effective steric size.

In organic chemistry, A-value refers to the free energy difference between the axial and equatorial positions of a substituent on cyclohexane, used as a measure of its effective steric size. This meaning comes from Winstein (1955) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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Nearby constructs

Winstein-Holness equation1 fields · 1 citationsanchor · a standalone constructenergy5 fields · 10 citationsjingle · one word, five constructsfree energy3 fields · 7 citationsjingle · one word, three constructs

References

  1. Winstein, S., & Holness, N. J. (1955). Neighboring Carbon and Hydrogen. XIX. t-Butylcyclohexyl Derivatives. Quantitative Conformational Analysis. Journal of the American Chemical Society, 77(21), 5562-5578. https://doi.org/10.1021/ja01626a037

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