Construct · 1 fields · 1 citations

allylic strain: a standalone construct

One name. One construct. A landmark on the map.

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allylicstrain1 CONSTRUCTAllylic strainHOFFMANN · ORGANIC CHEMISTRY

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Organic chemistry

steric strain between substituents on the ends of an allylic system that restricts conformations and controls stereoselectivity.

In organic chemistry, allylic strain refers to steric strain between substituents on the ends of an allylic system that restricts conformations and controls stereoselectivity. This meaning comes from Hoffmann (1989) in Chemical Reviews.[1]

Unit
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Measured by

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Nearby constructs

strain4 fields · 5 citationsjingle · one word, four constructs

References

  1. Hoffmann, R. W. (1989). Allylic 1,3-strain as a controlling factor in stereoselective transformations. Chemical Reviews, 89(8), 1841-1860. https://doi.org/10.1021/cr00098a009

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