Construct · 1 fields · 1 citations

angular overlap model: a standalone construct

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Coordination chemistry

a ligand field approach that splits d-orbital energies into separate sigma and pi contributions from each ligand according to its angular overlap with the metal.

In coordination chemistry, angular overlap model refers to a ligand field approach that splits d-orbital energies into separate sigma and pi contributions from each ligand according to its angular overlap with the metal. This meaning comes from Schäffer (1965) in Molecular Physics.[1]

Unit
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Nearby constructs

coordination4 fields · 4 citationsjingle · one word, four constructs field3 fields · 5 citationsjingle · one word, three constructs ligand2 fields · 2 citationsinvariant · one construct, two systems

References

Schäffer, C. E., & Jørgensen, C. K. (1965). The angular overlap model, an attempt to revive the ligand field approaches. Molecular Physics, 9(5), 401-412. https://doi.org/10.1080/00268976500100551

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