Construct · 1 fields · 1 citations

anomeric effect: a standalone construct

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Organic chemistry

the preference of electronegative substituents next to a ring heteroatom for the axial position, against steric expectations.

In organic chemistry, anomeric effect refers to the preference of electronegative substituents next to a ring heteroatom for the axial position, against steric expectations. This meaning comes from Juaristi (1992) in Tetrahedron.[1]

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Nearby constructs

position3 fields · 6 citationsjingle · one word, three constructs preference4 fields · 7 citationsjingle · one word, four constructs ring3 fields · 3 citationsjingle · one word, three constructs

References

Juaristi, E., & Cuevas, G. (1992). Recent studies of the anomeric effect. Tetrahedron, 48(24), 5019-5087. https://doi.org/10.1016/s0040-4020(01)90118-8

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