Construct · 1 fields · 1 citations

Corey-Bakshi-Shibata reduction: a standalone construct

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Corey-Bakshi-Shibatareduction1 CONSTRUCTCorey-Bakshi-ShibataCOREY · ORGANIC CHEMISTRY

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Organic chemistry

enantioselective borane reduction of prochiral ketones catalyzed by a chiral oxazaborolidine that organizes ketone and borane in a defined geometry.

In organic chemistry, Corey-Bakshi-Shibata reduction refers to enantioselective borane reduction of prochiral ketones catalyzed by a chiral oxazaborolidine that organizes ketone and borane in a defined geometry. This meaning comes from Corey (1987) in Journal of the American Chemical Society.[1]

Unit
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Measured by

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Nearby constructs

reduction5 fields · 5 citationsjingle · one word, five constructs

References

  1. Corey, E. J., Bakshi, R. K., & Shibata, S. (1987). Highly enantioselective borane reduction of ketones catalyzed by chiral oxazaborolidines. Mechanism and synthetic implications. Journal of the American Chemical Society, 109(18), 5551-5553. https://doi.org/10.1021/ja00252a056

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