Construct · 1 fields · 1 citations

Cram chelation model: a standalone construct

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Organic chemistry

a model of nucleophilic addition to carbonyls with a nearby donor group, where metal chelation locks the conformation and sets the stereochemistry.

In organic chemistry, Cram chelation model refers to a model of nucleophilic addition to carbonyls with a nearby donor group, where metal chelation locks the conformation and sets the stereochemistry. This meaning comes from Cram (1959) in Journal of the American Chemical Society.[1]

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Nearby constructs

chelation2 fields · 2 citationsjingle · one word, two constructs conformation2 fields · 2 citationsjingle · one word, two constructs group4 fields · 4 citationsjingle · one word, four constructs

References

Cram, D. J., & Kopecky, K. R. (1959). Studies in Stereochemistry. XXX. Models for Steric Control of Asymmetric Induction. Journal of the American Chemical Society, 81(11), 2748-2755. https://doi.org/10.1021/ja01520a036

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