Construct · 1 fields · 1 citations

Curtin-Hammett principle: a standalone construct

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Organic chemistry

when conformers interconvert faster than they react, product ratios depend on transition-state energies rather than on conformer populations.

In organic chemistry, Curtin-Hammett principle refers to when conformers interconvert faster than they react, product ratios depend on transition-state energies rather than on conformer populations. This meaning comes from Seeman (1983) in Chemical Reviews.[1]

Unit
Recovery means
Measured by

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Nearby constructs

product3 fields · 3 citationsjingle · one word, three constructs

References

Seeman, J. I. (1983). Effect of conformational change on reactivity in organic chemistry. Evaluations, applications, and extensions of Curtin-Hammett Winstein-Holness kinetics. Chemical Reviews, 83(2), 83-134. https://doi.org/10.1021/cr00054a001

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