Construct · 1 fields · 1 citations

dynamic matching: a standalone construct

One name. One construct. A landmark on the map.

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dynamicmatching1 CONSTRUCTDynamic matchingCARPENTER · CHEMICAL KINETICS

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Chemical kinetics

the idea that momentum carried from a transition state into a shallow intermediate steers products, so product ratios reflect dynamics rather than statistical equilibration.

In chemical kinetics, dynamic matching refers to the idea that momentum carried from a transition state into a shallow intermediate steers products, so product ratios reflect dynamics rather than statistical equilibration. This meaning comes from Carpenter (1985) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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Nearby constructs

dynamics3 fields · 3 citationsjingle · one word, three constructsmatching4 fields · 4 citationsjingle · one word, four constructsmomentum7 fields · 14 citationsjingle · one name, six constructs

References

  1. Carpenter, B. K. (1985). Trajectories through an intermediate at a fourfold branch point. Implications for the stereochemistry of biradical reactions. Journal of the American Chemical Society, 107(20), 5730-5732. https://doi.org/10.1021/ja00306a021

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