Construct · 1 fields · 1 citations

Fischer carbene: a standalone construct

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Fischercarbene1 CONSTRUCTFischer carbeneFISCHER · ORGANOMETALLIC

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Organometallic chemistry

a metal carbene with an electrophilic carbon, typically on a low-valent metal with pi-acceptor ligands and a heteroatom substituent.

In organometallic chemistry, Fischer carbene refers to a metal carbene with an electrophilic carbon, typically on a low-valent metal with pi-acceptor ligands and a heteroatom substituent. This meaning comes from Fischer (1964) in Angewandte Chemie International Edition in English.[1]

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References

  1. Fischer, E. O., & Maasböl, A. (1964). On the Existence of a Tungsten Carbonyl Carbene Complex. Angewandte Chemie International Edition in English, 3(8), 580-581. https://doi.org/10.1002/anie.196405801

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