Construct · 1 fields · 1 citations

gauche effect: a standalone construct

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gaucheeffect1 CONSTRUCTGauche effectWOLFE · ORGANIC CHEMISTRY

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Organic chemistry

the preference of certain molecules with neighboring electronegative substituents for the gauche rather than the anti conformation.

In organic chemistry, gauche effect refers to the preference of certain molecules with neighboring electronegative substituents for the gauche rather than the anti conformation. This meaning comes from Wolfe (1972) in Accounts of Chemical Research.[1]

Unit
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Nearby constructs

accounts1 fields · 1 citationsanchor · a standalone constructconformation2 fields · 2 citationsjingle · one word, two constructsneighboring1 fields · 1 citationsanchor · a standalone construct

References

  1. Wolfe, S. (1972). Gauche effect. Stereochemical consequences of adjacent electron pairs and polar bonds. Accounts of Chemical Research, 5(3), 102-111. https://doi.org/10.1021/ar50051a003

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