Construct · 1 fields · 1 citations

Grote-Hynes theory: a standalone construct

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Chemical kinetics

a correction to transition state theory in which the solvent's time-dependent friction near the barrier top determines how many barrier crossings recross.

In chemical kinetics, Grote-Hynes theory refers to a correction to transition state theory in which the solvent's time-dependent friction near the barrier top determines how many barrier crossings recross. This meaning comes from Grote (1980) in The Journal of Chemical Physics.[1]

Unit
Recovery means
Measured by

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Nearby constructs

barrier4 fields · 7 citationsjingle · one word, four constructs friction6 fields · 12 citationsjingle · one name, six constructs solvent1 fields · 1 citationsanchor · a standalone construct

References

Grote, R. F., & Hynes, J. T. (1980). The stable states picture of chemical reactions. II. Rate constants for condensed and gas phase reaction models. The Journal of Chemical Physics, 73(6), 2715-2732. https://doi.org/10.1063/1.440485

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