Construct · 1 fields · 1 citations

Hiyama coupling: a standalone construct

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Organic chemistry

palladium-catalyzed cross-coupling of organosilanes with organic halides, made possible by fluoride activation of the silicon partner.

In organic chemistry, Hiyama coupling refers to palladium-catalyzed cross-coupling of organosilanes with organic halides, made possible by fluoride activation of the silicon partner. This meaning comes from Hatanaka (1988) in The Journal of Organic Chemistry.[1]

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Nearby constructs

activation4 fields · 4 citationsjingle · one word, four constructs coupling4 fields · 4 citationsjingle · one word, four constructs

References

Hatanaka, Y., & Hiyama, T. (1988). Cross-coupling of organosilanes with organic halides mediated by a palladium catalyst and tris(diethylamino)sulfonium difluorotrimethylsilicate. The Journal of Organic Chemistry, 53(4), 918-920. https://doi.org/10.1021/jo00239a056

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