Construct · 1 fields · 1 citations

iminium catalysis: a standalone construct

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Organic chemistry

activation mode in which a chiral secondary amine condenses with an enal to form an iminium ion, lowering its LUMO for enantioselective reactions.

In organic chemistry, iminium catalysis refers to activation mode in which a chiral secondary amine condenses with an enal to form an iminium ion, lowering its LUMO for enantioselective reactions. This meaning comes from Ahrendt (2000) in Journal of the American Chemical Society.[1]

Unit
Recovery means
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Nearby constructs

activation4 fields · 4 citationsjingle · one word, four constructs catalysis3 fields · 4 citationsjingle · one word, three constructs form4 fields · 7 citationsjingle · one word, four constructs

References

Ahrendt, K. A., Borths, C. J., & MacMillan, D. W. C. (2000). New Strategies for Organic Catalysis: The First Highly Enantioselective Organocatalytic Diels−Alder Reaction. Journal of the American Chemical Society, 122(17), 4243-4244. https://doi.org/10.1021/ja000092s

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