Construct · 1 fields · 1 citations

inverted ligand field: a standalone construct

One name. One construct. A landmark on the map.

● anchor · a standalone construct Nearest construct by meaning·not indexed
invertedligand field1 CONSTRUCTInverted ligand fieldHOFFMANN · COORDINATION

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Coordination chemistry

a bonding situation in which the metal-ligand antibonding orbitals are mainly ligand-based rather than metal-based, which upsets usual assumptions about oxidation state and d-electron count.

In coordination chemistry, inverted ligand field refers to a bonding situation in which the metal-ligand antibonding orbitals are mainly ligand-based rather than metal-based, which upsets usual assumptions about oxidation state and d-electron count. This meaning comes from Hoffmann (2016) in Chemical Reviews.[1]

Unit
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Nearby constructs

coordination4 fields · 4 citationsjingle · one word, four constructscount2 fields · 2 citationsjingle · one word, two constructsfield3 fields · 5 citationsjingle · one word, three constructs

References

  1. Hoffmann, R., Alvarez, S., Mealli, C., Falceto, A., Cahill, T. J., Zeng, T., & Manca, G. (2016). From Widely Accepted Concepts in Coordination Chemistry to Inverted Ligand Fields. Chemical Reviews, 116(14), 8173-8192. https://doi.org/10.1021/acs.chemrev.6b00251

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