Construct · 1 fields · 1 citations

ligand repulsive energy: a standalone construct

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Organometallic chemistry

a molecular mechanics measure of a ligand's steric demand, defined from the repulsive energy change as its metal distance is varied.

In organometallic chemistry, ligand repulsive energy refers to a molecular mechanics measure of a ligand's steric demand, defined from the repulsive energy change as its metal distance is varied. This meaning comes from Brown (1992) in Inorganic Chemistry.[1]

Unit
Recovery means
Measured by

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Nearby constructs

demand4 fields · 4 citationsjingle · one word, four constructs energy5 fields · 10 citationsjingle · one word, five constructs ligand2 fields · 2 citationsinvariant · one construct, two systems

References

Brown, T. L. (1992). A molecular mechanics model of ligand effects. 3. A new measure of ligand steric effects. Inorganic Chemistry, 31(7), 1286-1294. https://doi.org/10.1021/ic00033a029

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