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meta effect in photochemistry: a standalone construct

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meta effect inphotochemistry1 CONSTRUCTMeta effect inZIMMERMAN · PHOTOCHEMISTRY

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Photochemistry

the finding that substituents meta to a reacting site exert stronger electronic effects in excited states than para substituents, reversing ground-state patterns.

In photochemistry, meta effect in photochemistry refers to the finding that substituents meta to a reacting site exert stronger electronic effects in excited states than para substituents, reversing ground-state patterns. This meaning comes from Zimmerman (1963) in Journal of the American Chemical Society.[1]

Unit
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Measured by

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References

  1. Zimmerman, H. E., & Sandel, V. R. (1963). Mechanistic Organic Photochemistry. II. Solvolytic Photochemical Reactions. Journal of the American Chemical Society, 85(7), 915-922. https://doi.org/10.1021/ja00890a019

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