Construct · 1 fields · 1 citations

Mitsunobu reaction: a standalone construct

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Mitsunobureaction1 CONSTRUCTMitsunobu reactionMITSUNOBU · ORGANIC CHEMISTRY

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Organic chemistry

condensation of an alcohol with an acidic nucleophile through a phosphonium intermediate formed from triphenylphosphine and an azodicarboxylate, typically with inversion of configuration.

In organic chemistry, Mitsunobu reaction refers to condensation of an alcohol with an acidic nucleophile through a phosphonium intermediate formed from triphenylphosphine and an azodicarboxylate, typically with inversion of configuration. This meaning comes from Mitsunobu (1967) in Bulletin of the Chemical Society of Japan.[1]

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Nearby constructs

condensation4 fields · 4 citationsjingle · one word, four constructsconfiguration4 fields · 6 citationsjingle · one word, four constructsinversion4 fields · 4 citationsjingle · one word, four constructs

References

  1. Mitsunobu, O., & Yamada, M. (1967). Preparation of Esters of Carboxylic and Phosphoric Acid via Quaternary Phosphonium Salts. Bulletin of the Chemical Society of Japan, 40(10), 2380-2382. https://doi.org/10.1246/bcsj.40.2380

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