Construct · 1 fields · 1 citations

negative hyperconjugation: a standalone construct

One name. One construct. A landmark on the map.

● anchor · a standalone construct Nearest construct by meaning·not indexed
negativehyperconjugation1 CONSTRUCTNegativeVON RAGUÉ SCHLEYER · ORGANIC

A single standalone construct; nearby constructs are located against it in the Collider. Tap a field for its definition, unit, and measures.

Organic chemistry

stabilization from donation of a filled lone pair or pi orbital into a neighbouring sigma antibonding orbital.

In organic chemistry, negative hyperconjugation refers to stabilization from donation of a filled lone pair or pi orbital into a neighbouring sigma antibonding orbital. This meaning comes from von Ragué Schleyer (1983) in Tetrahedron.[1]

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Nearby constructs

hyperconjugation1 fields · 1 citationsanchor · a standalone constructorbital1 fields · 1 citationsanchor · one construct, one fieldsigma4 fields · 5 citationsjingle · one word, four constructs

References

  1. von Ragué Schleyer, P., & Kos, A. J. (1983). The importance of negative (anionic) hyperconjugation. Tetrahedron, 39(7), 1141-1150. https://doi.org/10.1016/s0040-4020(01)91877-0

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