Construct · 1 fields · 1 citations

Negishi coupling: a standalone construct

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Organic chemistry

palladium- or nickel-catalyzed cross-coupling of organozinc reagents with organic halides to form carbon-carbon bonds with high selectivity.

In organic chemistry, Negishi coupling refers to palladium- or nickel-catalyzed cross-coupling of organozinc reagents with organic halides to form carbon-carbon bonds with high selectivity. This meaning comes from King (1977) in Journal of the Chemical Society, Chemical Communications.[1]

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Nearby constructs

coupling4 fields · 4 citationsjingle · one word, four constructs form4 fields · 7 citationsjingle · one word, four constructs selectivity4 fields · 5 citationsjingle · one word, four constructs

References

King, A. O., Okukado, N., & Negishi, E. (1977). Highly general stereo-, regio-, and chemo-selective synthesis of terminal and internal conjugated enynes by the Pd-catalysed reaction of alkynylzinc reagents with alkenyl halides. Journal of the Chemical Society, Chemical Communications, 683. https://doi.org/10.1039/c39770000683

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