Construct · 1 fields · 1 citations

neighbouring group participation: a standalone construct

One name. One construct. A landmark on the map.

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Organic chemistry

rate enhancement and stereochemical control when a group within the substrate acts as an internal nucleophile during substitution.

In organic chemistry, neighbouring group participation refers to rate enhancement and stereochemical control when a group within the substrate acts as an internal nucleophile during substitution. This meaning comes from Winstein (1948) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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Nearby constructs

control4 fields · 5 citationsjingle · one word, four constructs group4 fields · 4 citationsjingle · one word, four constructs substitution4 fields · 4 citationsjingle · one word, four constructs

References

Winstein, S., & Grunwald, E. (1948). The Role of Neighboring Groups in Replacement Reactions. XIII. General Theory of Neighboring Groups and Reactivity. Journal of the American Chemical Society, 70(2), 828-837. https://doi.org/10.1021/ja01182a114

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