Construct · 1 fields · 1 citations

percent buried volume: a standalone construct

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Organometallic chemistry

a steric descriptor giving the share of a sphere around the metal that a ligand occupies, used to compare phosphine and carbene ligands.

In organometallic chemistry, percent buried volume refers to a steric descriptor giving the share of a sphere around the metal that a ligand occupies, used to compare phosphine and carbene ligands. This meaning comes from Clavier (2010) in Chemical Communications.[1]

Unit
Recovery means
Measured by

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Nearby constructs

ligand2 fields · 2 citationsinvariant · one construct, two systems share2 fields · 2 citationsjingle · one word, two constructs volume3 fields · 4 citationsjingle · one word, three constructs

References

Clavier, H., & Nolan, S. P. (2010). Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry. Chemical Communications, 46(6), 841. https://doi.org/10.1039/b922984a

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