Construct · 1 fields · 1 citations

Perlin effect: a standalone construct

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Perlineffect1 CONSTRUCTPerlin effectWOLFE · ORGANIC CHEMISTRY

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Organic chemistry

axial C-H bonds next to a ring oxygen or nitrogen show a smaller one-bond carbon-hydrogen NMR coupling constant than equatorial ones, traced to stereoelectronic electron donation.

In organic chemistry, Perlin effect refers to axial C-H bonds next to a ring oxygen or nitrogen show a smaller one-bond carbon-hydrogen NMR coupling constant than equatorial ones, traced to stereoelectronic electron donation. This meaning comes from Wolfe (1990) in Canadian Journal of Chemistry.[1]

Unit
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Measured by

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Nearby constructs

constant2 fields · 2 citationsjingle · one word, two constructscoupling4 fields · 4 citationsjingle · one word, four constructsring3 fields · 3 citationsjingle · one word, three constructs

References

  1. Wolfe, S., Pinto, B. M., Varma, V., & Leung, R. Y. N. (1990). The Perlin Effect: bond lengths, bond strengths, and the origins of stereoelectronic effects upon one-bond C–H coupling constants. Canadian Journal of Chemistry, 68(7), 1051-1062. https://doi.org/10.1139/v90-164

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