Construct · 1 fields · 1 citations

persistent radical effect: a standalone construct

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Organic chemistry

the kinetic principle that a persistent radical builds up and steers cross-coupling with a transient radical over self-termination.

In organic chemistry, persistent radical effect refers to the kinetic principle that a persistent radical builds up and steers cross-coupling with a transient radical over self-termination. This meaning comes from Fischer (2001) in Chemical Reviews.[1]

Unit
Recovery means
Measured by

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Nearby constructs

radical3 fields · 5 citationsjingle · one word, three constructs transient3 fields · 3 citationsinvariant · one construct, three systems

References

Fischer, H. (2001). The Persistent Radical Effect: A Principle for Selective Radical Reactions and Living Radical Polymerizations. Chemical Reviews, 101(12), 3581-3610. https://doi.org/10.1021/cr990124y

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