Construct · 1 fields · 1 citations

Polanyi rules: a standalone construct

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Polanyirules1 CONSTRUCTPolanyi rulesPOLANYI · PHYSICAL CHEMISTRY

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Physical chemistry

rules relating barrier location to energy disposal: early barriers favor translational energy for reaction and give vibrationally excited products, late barriers favor vibration.

In physical chemistry, Polanyi rules refers to rules relating barrier location to energy disposal: early barriers favor translational energy for reaction and give vibrationally excited products, late barriers favor vibration. This meaning comes from Polanyi (1972) in Accounts of Chemical Research.[1]

Unit
Recovery means
Measured by

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Nearby constructs

accounts1 fields · 1 citationsanchor · a standalone constructbarrier4 fields · 7 citationsjingle · one word, four constructsenergy5 fields · 10 citationsjingle · one word, five constructs

References

  1. Polanyi, J. C. (1972). Concepts in reaction dynamics. Accounts of Chemical Research, 5(5), 161-168. https://doi.org/10.1021/ar50053a001

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