Construct · 1 fields · 1 citations

post-transition state bifurcation: a standalone construct

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post-transitionstate bifurcation1 CONSTRUCTPost-transition stateESS · ORGANIC CHEMISTRY

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Organic chemistry

a potential energy surface on which one transition state leads to two products, so dynamics rather than barrier heights set the product ratio.

In organic chemistry, post-transition state bifurcation refers to a potential energy surface on which one transition state leads to two products, so dynamics rather than barrier heights set the product ratio. This meaning comes from Ess (2008) in Angewandte Chemie International Edition.[1]

Unit
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Nearby constructs

barrier4 fields · 7 citationsjingle · one word, four constructsbifurcation3 fields · 5 citationsjingle · one word, three constructsdynamics3 fields · 3 citationsjingle · one word, three constructs

References

  1. Ess, D. H., Wheeler, S. E., Iafe, R. G., Xu, L., Çelebi‐Ölçüm, N., & Houk, K. N. (2008). Bifurcations on Potential Energy Surfaces of Organic Reactions. Angewandte Chemie International Edition, 47(40), 7592-7601. https://doi.org/10.1002/anie.200800918

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