Construct · 1 fields · 1 citations

self-regeneration of stereocenters: a standalone construct

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self-regenerationof stereocenters1 CONSTRUCTSelf-regeneration ofSEEBACH · ORGANIC CHEMISTRY

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Organic chemistry

strategy in which a temporary stereocenter holds the chirality of an original one while it is destroyed and rebuilt, so a chiral compound can be substituted without racemization.

In organic chemistry, self-regeneration of stereocenters refers to strategy in which a temporary stereocenter holds the chirality of an original one while it is destroyed and rebuilt, so a chiral compound can be substituted without racemization. This meaning comes from Seebach (1996) in Angewandte Chemie International Edition in English.[1]

Unit
Recovery means
Measured by

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Nearby constructs

chirality4 fields · 8 citationsjingle · one word, four constructs of handednesscompound3 fields · 3 citationsjingle · one word, three constructsstrategy4 fields · 4 citationsjingle · one word, four constructs

References

  1. Seebach, D., Sting, A. R., & Hoffmann, M. (1996). Self‐Regeneration of Stereocenters (SRS): Applications, Limitations, and Abandonment of a Synthetic Principle. Angewandte Chemie International Edition in English, 35(23-24), 2708-2748. https://doi.org/10.1002/anie.199627081

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