Construct · 1 fields · 1 citations

Sharpless asymmetric dihydroxylation: a standalone construct

One name. One construct. A landmark on the map.

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Organic chemistry

osmium-catalyzed conversion of alkenes to chiral diols in which a cinchona alkaloid ligand both speeds the reaction and sets the enantioselectivity.

In organic chemistry, Sharpless asymmetric dihydroxylation refers to osmium-catalyzed conversion of alkenes to chiral diols in which a cinchona alkaloid ligand both speeds the reaction and sets the enantioselectivity. This meaning comes from Jacobsen (1988) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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Nearby constructs

conversion5 fields · 5 citationsjingle · one word, four turnings ligand2 fields · 2 citationsinvariant · one construct, two systems reaction4 fields · 4 citationsjingle · one word, four constructs

References

Jacobsen, E. N., Marko, I., Mungall, W. S., Schroeder, G., & Sharpless, K. B. (1988). Asymmetric dihydroxylation via ligand-accelerated catalysis. Journal of the American Chemical Society, 110(6), 1968-1970. https://doi.org/10.1021/ja00214a053

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