Construct · 1 fields · 1 citations

Swain-Schaad relationship: a standalone construct

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Swain-Schaadrelationship1 CONSTRUCTSwain-SchaadSWAIN · CHEMICAL KINETICS

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Chemical kinetics

a fixed exponential relation between hydrogen, deuterium and tritium kinetic isotope effects, used to test whether tunneling or coupled motions distort semiclassical behavior.

In chemical kinetics, Swain-Schaad relationship refers to a fixed exponential relation between hydrogen, deuterium and tritium kinetic isotope effects, used to test whether tunneling or coupled motions distort semiclassical behavior. This meaning comes from Swain (1958) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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Nearby constructs

relation4 fields · 4 citationsjingle · one word, four constructstunneling4 fields · 7 citationsjingle · one word, four constructs

References

  1. Swain, C. G., Stivers, E. C., Reuwer, J. F., & Schaad, L. J. (1958). Use of Hydrogen Isotope Effects to Identify the Attacking Nucleophile in the Enolization of Ketones Catalyzed by Acetic Acid. Journal of the American Chemical Society, 80(21), 5885-5893. https://doi.org/10.1021/ja01554a077

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