Construct · 1 fields · 1 citations

Swain-Scott equation: a standalone construct

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Physical chemistry

a linear free energy relation expressing nucleophilic substitution rates as the product of a nucleophile constant and a substrate sensitivity constant.

In physical chemistry, Swain-Scott equation refers to a linear free energy relation expressing nucleophilic substitution rates as the product of a nucleophile constant and a substrate sensitivity constant. This meaning comes from Swain (1953) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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Nearby constructs

constant2 fields · 2 citationsjingle · one word, two constructs energy5 fields · 10 citationsjingle · one word, five constructs free energy3 fields · 7 citationsjingle · one word, three constructs

References

Swain, C. G., & Scott, C. B. (1953). Quantitative Correlation of Relative Rates. Comparison of Hydroxide Ion with Other Nucleophilic Reagents toward Alkyl Halides, Esters, Epoxides and Acyl Halides. Journal of the American Chemical Society, 75(1), 141-147. https://doi.org/10.1021/ja01097a041

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