Construct · 1 fields · 1 citations

tunneling control: a standalone construct

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tunnelingcontrol1 CONSTRUCTTunneling controlSCHREINER · PHYSICAL CHEMISTRY

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Physical chemistry

control of reaction outcome by quantum mechanical tunneling, so that the product formed fastest through the barrier differs from kinetic or thermodynamic expectations.

In physical chemistry, tunneling control refers to control of reaction outcome by quantum mechanical tunneling, so that the product formed fastest through the barrier differs from kinetic or thermodynamic expectations. This meaning comes from Schreiner (2017) in Journal of the American Chemical Society.[1]

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Nearby constructs

barrier4 fields · 7 citationsjingle · one word, four constructscontrol4 fields · 5 citationsjingle · one word, four constructsproduct3 fields · 3 citationsjingle · one word, three constructs

References

  1. Schreiner, P. R. (2017). Tunneling Control of Chemical Reactions: The Third Reactivity Paradigm. Journal of the American Chemical Society, 139(43), 15276-15283. https://doi.org/10.1021/jacs.7b06035

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