Construct · 1 fields · 1 citations

umpolung: a standalone construct

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umpolung1 CONSTRUCTUmpolungSEEBACH · ORGANIC CHEMISTRY

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Organic chemistry

reversal of the normal polarity of a functional group carbon, so that a usually electrophilic site reacts as a nucleophile or the reverse.

In organic chemistry, umpolung refers to reversal of the normal polarity of a functional group carbon, so that a usually electrophilic site reacts as a nucleophile or the reverse. This meaning comes from Seebach (1979) in Angewandte Chemie International Edition in English.[1]

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Nearby constructs

group4 fields · 4 citationsjingle · one word, four constructsnormal3 fields · 7 citationsjingle · one word, three constructspolarity4 fields · 4 citationsjingle · one word, four constructs

References

  1. Seebach, D. (1979). Methods of Reactivity Umpolung. Angewandte Chemie International Edition in English, 18(4), 239-258. https://doi.org/10.1002/anie.197902393

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