Construct · 1 fields · 1 citations

Westheimer-Melander model: a standalone construct

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Chemical kinetics

the prediction that primary hydrogen kinetic isotope effects peak when the transferred proton sits symmetrically between donor and acceptor in the transition state.

In chemical kinetics, Westheimer-Melander model refers to the prediction that primary hydrogen kinetic isotope effects peak when the transferred proton sits symmetrically between donor and acceptor in the transition state. This meaning comes from Westheimer (1961) in Chemical Reviews.[1]

Unit
Recovery means
Measured by

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Nearby constructs

kinetic isotope effect1 fields · 1 citationsanchor · a standalone construct model3 fields · 3 citationsjingle · one word, three constructs prediction3 fields · 4 citationsjingle · one word, three constructs

References

Westheimer, F. H. (1961). The Magnitude of the Primary Kinetic Isotope Effect for Compounds of Hydrogen and Deuterium. Chemical Reviews, 61(3), 265-273. https://doi.org/10.1021/cr60211a004

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