Construct · 1 fields · 1 citations

atropisomerism: a standalone construct

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Organic chemistry

stereoisomerism from hindered rotation about a single bond, defined operationally by isomers that interconvert slowly enough to be isolated.

In organic chemistry, atropisomerism refers to stereoisomerism from hindered rotation about a single bond, defined operationally by isomers that interconvert slowly enough to be isolated. This meaning comes from Ōki (1983) in Topics in Stereochemistry.[1]

Unit
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bond2 fields · 2 citationsjingle · one word, two constructs rotation4 fields · 7 citationsjingle · one word, four constructs

References

Ōki, M. (1983). Recent Advances in Atropisomerism. In Topics in Stereochemistry (pp. 1-81). Wiley. https://doi.org/10.1002/9780470147238.ch1

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