Construct · 1 fields · 1 citations

Bredt's rule: a standalone construct

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Organic chemistry

a double bond cannot sit at the bridgehead of a small bridged bicyclic ring system because the needed overlap of p orbitals cannot be reached.

In organic chemistry, Bredt's rule refers to a double bond cannot sit at the bridgehead of a small bridged bicyclic ring system because the needed overlap of p orbitals cannot be reached. This meaning comes from Bredt (1924) in Justus Liebigs Annalen der Chemie.[1]

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Nearby constructs

bond2 fields · 2 citationsjingle · one word, two constructs ring3 fields · 3 citationsjingle · one word, three constructs

References

Bredt, J. (1924). Über sterische Hinderung in Brückenringen (Bredtsche Regel) und über die meso ‐ trans ‐Stellung in kondensierten Ringsystemen des Hexamethylens. Justus Liebigs Annalen der Chemie, 437(1), 1-13. https://doi.org/10.1002/jlac.19244370102

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