Construct · 1 fields · 1 citations

Chalk-Harrod mechanism: a standalone construct

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Chalk-Harrodmechanism1 CONSTRUCTChalk-Harrod mechanismCHALK · ORGANOMETALLIC

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Organometallic chemistry

a catalytic cycle for olefin hydrosilylation through oxidative addition of silane, olefin insertion into the metal-hydride and silicon-carbon reductive elimination.

In organometallic chemistry, Chalk-Harrod mechanism refers to a catalytic cycle for olefin hydrosilylation through oxidative addition of silane, olefin insertion into the metal-hydride and silicon-carbon reductive elimination. This meaning comes from Chalk (1965) in Journal of the American Chemical Society.[1]

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Nearby constructs

catalysis3 fields · 4 citationsjingle · one word, three constructscycle4 fields · 4 citationsjingle · one word, four constructselimination4 fields · 7 citationsjingle · one word, four constructs

References

  1. Chalk, A. J., & Harrod, J. F. (1965). Homogeneous Catalysis. II. The Mechanism of the Hydrosilation of Olefins Catalyzed by Group VIII Metal Complexes. Journal of the American Chemical Society, 87(1), 16-21. https://doi.org/10.1021/ja01079a004

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