Construct · 1 fields · 1 citations

concerted metalation-deprotonation: a standalone construct

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Organometallic chemistry

a C-H activation pathway in which metal-carbon bond formation and proton removal by a coordinated base occur in one transition state.

In organometallic chemistry, concerted metalation-deprotonation refers to a C-H activation pathway in which metal-carbon bond formation and proton removal by a coordinated base occur in one transition state. This meaning comes from Gorelsky (2008) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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Nearby constructs

activation4 fields · 4 citationsjingle · one word, four constructs base3 fields · 4 citationsjingle · one word, three constructs bond2 fields · 2 citationsjingle · one word, two constructs

References

Gorelsky, S. I., Lapointe, D., & Fagnou, K. (2008). Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates. Journal of the American Chemical Society, 130(33), 10848-10849. https://doi.org/10.1021/ja802533u

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