Construct · 1 fields · 1 citations

Eigen-Wilkins mechanism: a standalone construct

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Coordination chemistry

complex formation in solution pictured as fast outer-sphere association of metal ion and ligand followed by rate-limiting loss of a coordinated solvent molecule.

In coordination chemistry, Eigen-Wilkins mechanism refers to complex formation in solution pictured as fast outer-sphere association of metal ion and ligand followed by rate-limiting loss of a coordinated solvent molecule. This meaning comes from Eigen (1965) in Advances in Chemistry.[1]

Unit
Recovery means
Measured by

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Nearby constructs

association4 fields · 4 citationsjingle · one word, four constructs complex4 fields · 4 citationsjingle · one word, four constructs coordination4 fields · 4 citationsjingle · one word, four constructs

References

Eigen, M., & Wilkins, R. G. (1965). The Kinetics and Mechanism of Formation of Metal Complexes. In Advances in Chemistry (pp. 55-80). AMERICAN CHEMICAL SOCIETY. https://doi.org/10.1021/ba-1965-0049.ch003

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