Construct · 1 fields · 1 citations

exo-anomeric effect: a standalone construct

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Organic chemistry

preference of the exocyclic alkoxy group of a glycoside for a rotation in which a lone pair of its oxygen lies antiperiplanar to the ring carbon-oxygen bond.

In organic chemistry, exo-anomeric effect refers to preference of the exocyclic alkoxy group of a glycoside for a rotation in which a lone pair of its oxygen lies antiperiplanar to the ring carbon-oxygen bond. This meaning comes from Lemieux (1969) in Canadian Journal of Chemistry.[1]

Unit
Recovery means
Measured by

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Nearby constructs

bond2 fields · 2 citationsjingle · one word, two constructs group4 fields · 4 citationsjingle · one word, four constructs preference4 fields · 7 citationsjingle · one word, four constructs

References

Lemieux, R. U., Pavia, A. A., Martin, J. C., & Watanabe, K. A. (1969). Solvation effects on conformational equilibria. Studies related to the conformational properties of 2-methoxytetrahydropyran and related methyl glycopyranosides. Canadian Journal of Chemistry, 47(23), 4427-4439. https://doi.org/10.1139/v69-731

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