Construct · 1 fields · 1 citations

Flippin-Lodge angle: a standalone construct

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Organic chemistry

angle describing the sideways offset of a nucleophile's approach toward a carbonyl carbon, complementing the Bürgi-Dunitz angle in models of addition.

In organic chemistry, Flippin-Lodge angle refers to angle describing the sideways offset of a nucleophile's approach toward a carbonyl carbon, complementing the Bürgi-Dunitz angle in models of addition. This meaning comes from Lodge (1987) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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Nearby constructs

Bürgi-Dunitz trajectory1 fields · 1 citationsanchor · a standalone construct offset3 fields · 5 citationsjingle · one word, three constructs

References

Lodge, E. P., & Heathcock, C. H. (1987). Acyclic stereoselection. 40. Steric effects, as well as.sigma.*-orbital energies, are important in diastereoface differentiation in additions to chiral aldehydes. Journal of the American Chemical Society, 109(11), 3353-3361. https://doi.org/10.1021/ja00245a027

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