Construct · 1 fields · 1 citations

Bürgi-Dunitz trajectory: a standalone construct

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Bürgi-Dunitztrajectory1 CONSTRUCTBürgi-Dunitz trajectoryBURGI · PHYSICAL ORGANIC

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Physical organic chemistry

preferred approach path of a nucleophile to a carbonyl carbon at an obtuse angle of about 105 to 107 degrees, inferred from crystal structure correlations.

In physical organic chemistry, Bürgi-Dunitz trajectory refers to preferred approach path of a nucleophile to a carbonyl carbon at an obtuse angle of about 105 to 107 degrees, inferred from crystal structure correlations. This meaning comes from Burgi (1973) in Journal of the American Chemical Society.[1]

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Nearby constructs

crystal4 fields · 4 citationsjingle · one word, four constructsFlippin-Lodge angle1 fields · 1 citationsanchor · a standalone constructpath3 fields · 3 citationsjingle · one word, three constructs

References

  1. Burgi, H. B., Dunitz, J. D., & Shefter, E. (1973). Geometrical reaction coordinates. II. Nucleophilic addition to a carbonyl group. Journal of the American Chemical Society, 95(15), 5065-5067. https://doi.org/10.1021/ja00796a058

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