Construct · 1 fields · 1 citations

Hughes-Ingold solvent rules: a standalone construct

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Hughes-Ingoldsolvent rules1 CONSTRUCTHughes-Ingold solventHUGHES · PHYSICAL ORGANIC

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Physical organic chemistry

qualitative predictions of how solvent polarity changes substitution and elimination rates according to whether charge is created, destroyed or spread in the transition state.

In physical organic chemistry, Hughes-Ingold solvent rules refers to qualitative predictions of how solvent polarity changes substitution and elimination rates according to whether charge is created, destroyed or spread in the transition state. This meaning comes from Hughes (1935) in Journal of the Chemical Society (Resumed).[1]

Unit
Recovery means
Measured by

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Nearby constructs

substitution4 fields · 4 citationsjingle · one word, four constructscharge1 fields · 2 citationsanchor · a standalone constructelimination4 fields · 7 citationsjingle · one word, four constructs

References

  1. Hughes, E. D., & Ingold, C. K. (1935). 55. Mechanism of substitution at a saturated carbon atom. Part IV. A discussion of constitutional and solvent effects on the mechanism, kinetics, velocity, and orientation of substitution. Journal of the Chemical Society (Resumed), 244. https://doi.org/10.1039/jr9350000244

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