Construct · 1 fields · 1 citations

indenyl effect: a standalone construct

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indenyleffect1 CONSTRUCTIndenyl effectHART-DAVIS · ORGANOMETALLIC

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Organometallic chemistry

the large rate increase for substitution at indenyl complexes compared with cyclopentadienyl analogues, attributed to easy ring slippage from eta5 to eta3.

In organometallic chemistry, indenyl effect refers to the large rate increase for substitution at indenyl complexes compared with cyclopentadienyl analogues, attributed to easy ring slippage from eta5 to eta3. This meaning comes from Hart-Davis (1969) in J. Chem. Soc. A.[1]

Unit
Recovery means
Measured by

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Nearby constructs

ring3 fields · 3 citationsjingle · one word, three constructsslippage2 fields · 2 citationsjingle · one word, two constructssubstitution4 fields · 4 citationsjingle · one word, four constructs

References

  1. Hart-Davis, A. J., & Mawby, R. J. (1969). Reactions of π-indenyl complexes of transition metals. Part I. Kinetics and mechanisms of reactions of tricarbonyl-π-indenylmethylmolybdenum with phosphorus( III ) ligands. J. Chem. Soc. A, 0(0), 2403-2407. https://doi.org/10.1039/j19690002403

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