Construct · 1 fields · 1 citations

Klopman-Salem equation: a standalone construct

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Klopman-Salemequation1 CONSTRUCTKlopman-Salem equationKLOPMAN · INORGANIC CHEMISTRY

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Inorganic chemistry

an expression splitting the energy of interaction between reacting partners into charge-controlled and frontier-orbital-controlled terms, linked to hard and soft reactivity.

In inorganic chemistry, Klopman-Salem equation refers to an expression splitting the energy of interaction between reacting partners into charge-controlled and frontier-orbital-controlled terms, linked to hard and soft reactivity. This meaning comes from Klopman (1968) in Journal of the American Chemical Society.[1]

Unit
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Nearby constructs

energy5 fields · 10 citationsjingle · one word, five constructsexpression4 fields · 4 citationsjingle · one word, four constructsinteraction3 fields · 7 citationsjingle · one word, three constructs

References

  1. Klopman, G. (1968). Chemical reactivity and the concept of charge- and frontier-controlled reactions. Journal of the American Chemical Society, 90(2), 223-234. https://doi.org/10.1021/ja01004a002

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