Construct · 1 fields · 1 citations

n-to-pi-star interaction: a standalone construct

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n-to-pi-starinteraction1 CONSTRUCTN-to-pi-star interactionNEWBERRY · SUPRAMOLECULAR

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Supramolecular chemistry

delocalization of a lone pair into the antibonding orbital of a nearby carbonyl, a weak force affecting protein and peptide conformation.

In supramolecular chemistry, n-to-pi-star interaction refers to delocalization of a lone pair into the antibonding orbital of a nearby carbonyl, a weak force affecting protein and peptide conformation. This meaning comes from Newberry (2017) in Accounts of Chemical Research.[1]

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Nearby constructs

accounts1 fields · 1 citationsanchor · a standalone constructconformation2 fields · 2 citationsjingle · one word, two constructsforce5 fields · 9 citationsjingle · one word, five constructs

References

  1. Newberry, R. W., & Raines, R. T. (2017). The n →π* Interaction. Accounts of Chemical Research, 50(8), 1838-1846. https://doi.org/10.1021/acs.accounts.7b00121

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