Construct · 1 fields · 1 citations

nephelauxetic effect: a standalone construct

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Coordination chemistry

the lowering of interelectronic repulsion within metal d-orbitals on complex formation, ordered by ligand as a gauge of metal-ligand covalency.

In coordination chemistry, nephelauxetic effect refers to the lowering of interelectronic repulsion within metal d-orbitals on complex formation, ordered by ligand as a gauge of metal-ligand covalency. This meaning comes from Schäffer (1958) in Journal of Inorganic and Nuclear Chemistry.[1]

Unit
Recovery means
Measured by

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Nearby constructs

complex4 fields · 4 citationsjingle · one word, four constructs coordination4 fields · 4 citationsjingle · one word, four constructs gauge2 fields · 4 citationsjingle · one word, two constructs

References

Schäffer, C. E., & Klixbüll Jørgensen, C. (1958). The nephelauxetic series of ligands corresponding to increasing tendency of partly covalent bonding. Journal of Inorganic and Nuclear Chemistry, 8, 143-148. https://doi.org/10.1016/0022-1902(58)80176-1

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