Construct · 1 fields · 1 citations

principle of nonperfect synchronization: a standalone construct

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principle of nonperfectsynchronization1 CONSTRUCTPrinciple of nonperfectBERNASCONI · ORGANIC CHEMISTRY

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Organic chemistry

the principle that when bond changes and charge delocalization lag one another in a transition state, the intrinsic barrier rises.

In organic chemistry, principle of nonperfect synchronization refers to the principle that when bond changes and charge delocalization lag one another in a transition state, the intrinsic barrier rises. This meaning comes from Bernasconi (1992) in Accounts of Chemical Research.[1]

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accounts1 fields · 1 citationsanchor · a standalone constructbarrier4 fields · 7 citationsjingle · one word, four constructsbond2 fields · 2 citationsjingle · one word, two constructs

References

  1. Bernasconi, C. F. (1992). The principle of nonperfect synchronization: more than a qualitative concept? Accounts of Chemical Research, 25(1), 9-16. https://doi.org/10.1021/ar00013a002

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