Construct · 1 fields · 1 citations

secondary orbital interaction: a standalone construct

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secondary orbitalinteraction1 CONSTRUCTSecondary orbitalHOFFMANN · ORGANIC CHEMISTRY

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Organic chemistry

favorable overlap between orbitals of a dienophile's substituents and the inner diene carbons, proposed to explain endo selectivity in cycloadditions.

In organic chemistry, secondary orbital interaction refers to favorable overlap between orbitals of a dienophile's substituents and the inner diene carbons, proposed to explain endo selectivity in cycloadditions. This meaning comes from Hoffmann (1965) in Journal of the American Chemical Society.[1]

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Nearby constructs

interaction3 fields · 7 citationsjingle · one word, three constructsorbital1 fields · 1 citationsanchor · one construct, one fieldselectivity4 fields · 5 citationsjingle · one word, four constructs

References

  1. Hoffmann, R., & Woodward, R. B. (1965). Orbital Symmetries and endo-exo Relationships in Concerted Cycloaddition Reactions. Journal of the American Chemical Society, 87(19), 4388-4389. https://doi.org/10.1021/ja00947a033

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