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small-curvature tunneling: a standalone construct

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small-curvaturetunneling1 CONSTRUCTSmall-curvatureLIU · CHEMICAL KINETICS

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Chemical kinetics

a multidimensional tunneling approximation in which the tunneling path cuts the corner of a gently curved reaction path, used with variational transition state theory.

In chemical kinetics, small-curvature tunneling refers to a multidimensional tunneling approximation in which the tunneling path cuts the corner of a gently curved reaction path, used with variational transition state theory. This meaning comes from Liu (1993) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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corner2 fields · 2 citationsjingle · one word, two constructspath3 fields · 3 citationsjingle · one word, three constructsreaction4 fields · 4 citationsjingle · one word, four constructs

References

  1. Liu, Y. P., Lynch, G. C., Truong, T. N., Lu, D. H., Truhlar, D. G., & Garrett, B. C. (1993). Molecular modeling of the kinetic isotope effect for the [1,5]-sigmatropic rearrangement of cis-1,3-pentadiene. Journal of the American Chemical Society, 115(6), 2408-2415. https://doi.org/10.1021/ja00059a041

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