Construct · 1 fields · 1 citations

Swain-Lupton parameters: a standalone construct

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Physical organic chemistry

separation of substituent effects into a field component and a resonance component, each expressed as a constant fitted across many reaction series.

In physical organic chemistry, Swain-Lupton parameters refers to separation of substituent effects into a field component and a resonance component, each expressed as a constant fitted across many reaction series. This meaning comes from Swain (1968) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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Nearby constructs

Bowen's reaction series1 fields · 3 citationsanchor · a standalone construct component3 fields · 5 citationsjingle · one word, three constructs constant2 fields · 2 citationsjingle · one word, two constructs

References

Swain, C. G., & Lupton, E. C. (1968). Field and resonance components of substituent effects. Journal of the American Chemical Society, 90(16), 4328-4337. https://doi.org/10.1021/ja01018a024

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