Construct · 1 fields · 1 citations

Thorpe-Ingold effect: a standalone construct

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Physical organic chemistry

acceleration of ring closure when geminal substituents on the connecting chain compress the internal bond angle and favor reactive conformations.

In physical organic chemistry, Thorpe-Ingold effect refers to acceleration of ring closure when geminal substituents on the connecting chain compress the internal bond angle and favor reactive conformations. This meaning comes from Beesley (1915) in J. Chem. Soc., Trans..[1]

Unit
Recovery means
Measured by

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Nearby constructs

acceleration4 fields · 4 citationsjingle · one word, four constructs bond2 fields · 2 citationsjingle · one word, two constructs chain3 fields · 3 citationsjingle · one word, three constructs

References

Beesley, R. M., Ingold, C. K., & Thorpe, J. F. (1915). CXIX.: The formation and stability of spiro-compounds. Part I. spiro-Compounds from cyclohexane. J. Chem. Soc., Trans., 107(0), 1080-1106. https://doi.org/10.1039/ct9150701080

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